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Sharpless asymmetric epoxidation [46], BINOL-Ti-catalyzed allylation [47], and asymmetric hydrogenation using BINAP-Ru catalysts [48] achieve high enantioselectivity

Notably, the population of the HOMO and LUMO orbitals equals one electron from the start of the CASSCF(14,13) geometric optimization when, in addition to the glutathione monoanion, the cyanocobalamin or aquacobalamin structures are involved

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D.FerrerasA.et al (2019)