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Although RpiA and RpiB are structurally very different, both enzymes catalyze the isomerization reaction via an enediol intermediate, using the linear form of the sugar

Notably, similar metabolic substrate-epigenetic modification frameworks exist for other metabolites, such as lauric acid, which modulates neural cell redox balance (Ramya et al., 2022) and regulates glucose transport via histone methylation and lncRNA HOTAIR (Ramya et al., 2024), highlighting the conserved nature of this regulatory mode and potential crosstalk with lactate-lactylation

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EBioMedicine 39 , 239254 (2019)